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The Hydrogen Atom

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Central Force: A force that is directed along the line connecting the center of the force and the particle, and whose magnitude depends only on the distance between the particle and the center 1. Hamiltonian Operator: An operator used in quantum mechanics to describe the total energy of a system. It includes both kinetic and potential energy terms 1. Laplacian Operator: A differential operator that describes the rate at which a function changes at a point relative to the average rate of change at nearby points. In spherical coordinates, it is used to transform the Schrödinger equation 1. Orbital Angular Momentum: A measure of the amount of rotation a particle has in a quantum system. It is quantized and described by the quantum number \( l \) 1. Spherical Harmonics: Functions that describe the angular part of the wave function in a spherically symmetric potential. They are used to solve the Schrödinger equation in spherical coordinates 1. Radial Distribution Function: A function that describes the probability of finding an electron at a certain distance from the nucleus. It is derived from the radial part of the wave function 1. Reduced Mass: The effective mass of a two-particle system, used to simplify the Schrödinger equation for systems like the hydrogen atom 1. Bohr Radius: The average distance between the nucleus and the electron in the ground state of the hydrogen atom, approximately 0.529 Å 1. Coulomb's Law: A law describing the force between two charged particles. In the context of the hydrogen atom, it describes the attractive force between the electron and the nucleus 1. Schrödinger Equation: A fundamental equation in quantum mechanics that describes how the quantum state of a physical system changes over time 1. Eigenfunctions and Eigenvalues: Solutions to the Schrödinger equation. Eigenfunctions describe the possible states of the system, and eigenvalues describe the corresponding energy levels 1. Quantum Numbers: Numbers that describe the properties of electrons in atoms. They include the principal quantum number \( n ), the orbital angular momentum quantum number \( l ), and the magnetic quantum number \( m \) 1. Degeneracy: The condition where multiple quantum states have the same energy level. In the hydrogen atom, energy levels are degenerate with respect to the quantum numbers \( l \) and \( m \) 1. Continuum States: States where the electron is not bound to the nucleus and has a positive energy. These states correspond to ionized atoms 1. Bound States: States where the electron is bound to the nucleus and has a negative energy. These states correspond to discrete energy levels 1. Zeeman Effect: The splitting of atomic spectral lines in the presence of an external magnetic field, due to the interaction between the magnetic field and the magnetic dipole moment of the electron 1. These terms should enhance your understanding of the chapter on the hydrogen atom. If you have any specific questions or need further explanations, feel free to ask!

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